If two molecules of hydrogen
gas are to react with one molecule of oxygen gas,
+
then we obtain the correct ratio of reactants by starting with two
volumes of hydrogen and one of oxygen (right). Since the reaction
produces two molecules of water, we can predict that if the product
obtained is water vapor, there will be two volumes of vapor. The
reaction by which ammonia, ,
is prepared from nitrogen and hydrogen gases is
+
Avogadro's principle tells us that if we want to carry out this
reaction without waste, we should begin with three times as much
hydrogen as nitrogen by volume at the same pressure and temperature.
The product, ammonia, will have twice the volume of the starting
, or half
the volume of the entire starting gas mixture. For gases, equal
volumes at the same temperature and pressure contain equal numbers
of moles.