As
we saw earlier, hydrogen and helium are created by the filing of
the 1s orbital. Lithium and beryllium arise from the placing
of the third and fourth electrons in the 2s orbital, and
boron through neon represent the subsequent filling of the three
2p orbitals with six more electrons. This completes the second
row of the table. The next lowest orbitals are the 3s and
the three 3p, and filling these orbitals produces the third
row of the table. It is common to write the electronic structure
of an atom by listing the orbitals in order of increasing n
and I values, and indicating the number of electrons
in each state with a superscript. As we have seen before, hydrogen
has the arrangement 1s,
and helium 1s.
Lithium is 1s
2s,
nitrogen is 1s
2s
2p,
and phosphorus, just below nitrogen in the third row, is 1s
2s
2p
3s
3p,
with the same sp
outer electronic configuration. In the "Electronic Structures
of the Elements" shown opposite and on pages 17,
18, 19 and 20,
orbitals being filled are depicted with a white background, and
completely filled orbitals are in color. An outer sp
arrangement with full s and p orbitals is the hallmark
of a noble gas (see table on previous page)
The energy gap between a p level and the next higher s
level is always greater than the gaps between other nearby levels.
This can be seen when the levels are stacked vertically, as on page
14. An unusually large amount of energy is required to add another
electron to an atom that already has a filled set of sp
orbitals, which is one reason why the noble gases are so unreactive.