Solution. The
reaction is a first-order
decomposition, because the rate depends on the first power of N205
concentration.
Notice that the order
of a reaction is an experimentally measured quantity, which does
not depend on how you write the equation for the reaction. Writing
the reaction with a coefficient 2 in front of the N205
term in the above example does not make the reaction second
order, any more than writing the same reaction as
would make it first order. To determine the order of a chemical
reaction, you must carry out real experiments.
Example.The
reduction of NO with H2,
is observed to depend on the NO and H2
concentrations in the following way:
with a dependence on the first power
of the H2 concentration rather than [H2]2
as the balanced equation might suggest. What is the order of the
overall reaction, and what is its order with respect to each of
the reacting substances?
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