How does a catalyst
provide a reaction mechanism with a lower activation
energy? Although inorganic and metallic catalysts have been
used for decades in the chemical and petroleum industries, we are
in the rather odd position of knowing more of the details of catalytic
mechanisms for enzymes than for these simpler catalysts, mainly
because of recent x-ray crystallographic structure analyses of enzyme
molecules.
Nevertheless, we can find a simple explanation
of why platinum, nickel, or other clean metal surfaces are effective
accelerators for reactions involving hydrogenation. Many
hydrogenation reactions, such as the following, are catalyzed by
metal surfaces:
It would be difficult to give these molecules
enough kinetic energy in the gas phase to cause them to react upon
colliding. The metal surface assists by adsorbing H2
molecules and pulling them apart into hydrogen atoms, which
bind to metal atoms at the surface.(opposite)
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