Concentrations involving such extreme powers of ten, extending
over 14 orders of magnitude, are clumsy to handle. In the discussion
of entropy in Chapter 13 we found it convenient to reduce a wide-ranging
quantity, probability, to more manageable numbers by taking the
logarithm
In chapter 14 we saw that standard free energies convey the same
information as equilibrium constants, but in a more compact logarithmic
form:
The value of logarithmic notation can be illustrated by the 10
X 10 X 10 stack of blocks at the right. The entire stack contains
1000 blocks. One face of the stack has 100 blocks, or 1/10 of the
whole.
One edge contains 10 blocks, or 1/100 of the stack, and one corner
block represents 1/1000 of the entire ensemble. The fractions represented
by the full block, face, edge, and corner, can be represented by
1 (or 100), 10-1, 10-2 , and 10-3.
We also can represent these different orders of magnitude by picking
out the negative exponents: 0, 1, 2, and 3. We can label these numbers
pF values if we define pF as the negative logarithm to base ten
of the fraction, F: