If a strong acid is added to a strong base, the product of hydrogen
and hydroxide ion concentrations will be high at first. Some of
these ions will recombine to form water until the product of [H+]
and [OH-] is again brought down to 10-14 mole2
liter-2 . This is the process of neutralization:
You can see from this that the neutralization of an acid and a
base really involves only the H+ and OH- ions,
and that other ions, Na+ and Cl- ions in this
case play only a passive role.
One mole of an acid that liberates one H+ per molecule,
or one mole of a base that produces one OH- per molecule,
are said to possess one equivalent of neutralizing power. For H2SO4,
which can release two protons per molecule, one mole of acid produces
two acid-base equivalents. When an acid and a base have exactly
neutralized one another, the number of equivalents of acid and base
must be the same, no matter what the concentrations of the individual
solutions.