Thus if Ag+ and Cl- are in balance in pure
water, and if more Cl- is added from another salt, then
Ag+ and Cl- will combine and precipitate as
solid AgCl until the product of [Ag+] and [Cl-]
once again is as low as Ksp for AgCl.
Solubility-constant expressions can be written for all slightly
soluble salts. Salts such as NaCI are very soluble, and their Ksp's
are effectively infinite, as far as solubility-product calculations
are concerned. Soluble and slightly soluble salts resemble strong
and weak acids, for although in theory there is no sharp demarcation
between the two categories, in practice the division between two
kinds of behavior is useful.
Solubility-product constants for various salts are given in the
table across. Remember that these come from equilibrium-constant
expressions, so if dissociation of a mole of a salt produces n moles
of one of the ions, that ion will appear in the Ksp expression
as the nth power of the concentration. For example,