12. Heat, Energy, and Chemical        Bonds   Previous PageNext Page
       Why is Fire Hot?

We can pull everything in this chapter together and bring it to a close by taking a second look at a question that was raised in Chapter 6 and again at the beginning of this chapter: Why is fire hot? The answer given previously was that oxidations give off heat because electrons in the product molecules are shifted toward the electronegative O or F atoms, and the molecules are more stable as a result. Now, with the aid of bond energies, we can stop being qualitative and put numbers to our argument.

The bond-energy values in the table on Page 22 support the assertion that the more the electrons in a bond are shifted toward an electronegative atom, the more stable the bond is. Single-bond energies between H and some other elements are

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