Third-law entropies, although they come purely from thermal
measurements, tell us something about molecular structure
if we know how to interpret them. These trends in entropies
are summarized below, and the entropies of the pure elements
as they ordinarily are encountered at room temperature are
listed on the periodic table on the right. All of the trends
in this table now should be understandable. Although entropy
originally began as a rather abstract concept involving heat,
it has a definite and visualizable meaning. Entropy is a direct
and quantitative measure of disorder.
|