These
four tetrahedral hybrid atomic orbitals are less stable than the
s and three p orbitals from which they came, because a small amount
of energy is required to bring the s-orbital energy up to the energy
of p before they can be hybridisied. This energy is regained several
times over whn bonds are formed between these hybrid orbitals and
orbitals from other atoms, so the mixing is possible. The four tetrahedral
orbitals are called sp
hybrid atomic orbitals.
Bonding in methane is illustrated at the right. Each of the four
sp
hybrid orbitals can combine with a hydrogen 1s atomic orbital to
form a localised bonding and antibonding pair of MO's. The antibonding
MO's are of no importance for methane because thwey are never occupied.
But when one of the bonding orbitals is filled with a pair of electrons,
a bond is formed between C and H. The sp
hybridisation leads to the observed molecular geometry with bond
angles of 109.5. Formation of four such bonds uses all of the 1s
orbitals of the four hydrogen atoms, and the s, p,
p
and p
orbitals from carbon. Filling the bonding orbitals requires all
four H electrons and all four second-shell electrons from C. The
1s orbital of carbon and its electron pair are not involved in the
bonding process.