Size
correlates beautifully with electronegativity. The larger the atom,
the weaker its hold on its outer-shell electrons, and the easier
it is for another atom to take them away. Electronegativities of
the representative elements are shown in color below. They range
from 0.7 for cesium at the lower left, to 4.0 for fluorine at the
upper right. We encountered cesium in Chapter 7, in connection with
the photoelectric effect, as the electron-losing metal that is employed
in electric eyes and photocells. It was mentioned previously that
the omission of the transition metals between Groups IIA and IIIA
was detectable by the sudden decrease in metallic radii, as shown
in the table on the lower left page. They also are responsible for
the unusual increase in electronegativity values (right), from 1.0
in Ca to 1.6 in Ga, and from 1.0 in Sr to 1.7 in In.
Lines connecting elements of equal electronegativity would extend
diagonally from the upper left of the table to the lower right.
Since electronegativity is chiefly responsible for determining chemical
behavior, the chemical properties of the elements also show diagonal
trends, as we have seen previously. The elements with amphoteric
oxides cut a diagonal swath down the table, from Be to Al, Ge, and
Sb. Weak, barely acidic oxyacids are formed by B, Si, As, and Te,
whereas the common strong laboratory oxyacids are derived from N
and S. This diagonality of properties also extends to the metal-nonmetal
boundary and the solid-gas boundary for nonmetals, as the table
at the beginning of the chapter indicates. The elements become more
metallic downward in each group, and to the left across each row.