The
coinage metals are unusually good conductors of electricity because
their electronic configurations are
instead of as
the periodic table would lead one to expect. In Chapter 8 we commented
on the special stability of filled
orbitals. This advantage in energy is enough to permit copper to
take one of the two electrons in the outer s orbital and
use it to fill the last of the d orbitals. This leaves the
s orbitals half empty, and facilitates the movement of s
electrons through the solid metal. (Because the d orbitals
are more deeply buried, electrons in these orbitals are not as free
to wander as are s orbital electrons.) The same mobility
of s electrons makes Cu, Ag, and Au good reflectors of light
(absorption and immediate reemission at the same wavelengths) and
conductors of heat. This is why copper and silver are employed as
conductors in electronic circuitry, and why artificial satellites
are sometimes gold-plated to reflect sunlight and keep the temperature
down.
All of the s and d orbitals are filled in Zn, Cd,
and Hg, thereby reducing the mobility of electrons from one atom
to the next, and lowering the electrical and thermal conductivity
of the metals. With all outer electrons paired, interactions between
atoms are lessened, which makes the solids soft and low-melting.
Mercury, the transition metal of largest atomic size, is a liquid
above -390°C, but this is not a fundamental chemical difference
because on a warm summer day cesium and gallium are liquids also.