Stereospecific amino acid synthesis; preparation of the γ-anion derived from glutamic acid

Symplectic ID: 
42879
Source: 
Scopus
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1
Last Synced with Symplectic: 
Monday, 14 September, 2026 - 15:08
DOI: 
10.1039/C39880000828
Publication Date: 
Friday, 1 January, 1988
First Page: 
828
Last Page: 
829
Authors: 
Baldwin, JE
North, M
Flinn, A
Moloney, MG
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0
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Abstract: 
Reaction of α-t-butyl γ-methyl N-trityl-L-glutamate (7) with lithium isopropylcyclohexylamide in hexane leads to the specific formation of the γ-ester enolate, a potential synthetic equivalent to the γ-anion synthon for stereospecific α-amino acid synthesis.
ISSN: 
0022-4936
Journal Title: 
Journal of the Chemical Society, Chemical Communications
Issue: 
12
ID at Source: 
2-s2.0-37049077684
Publication Status: 
Published
Open access: 
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SSO preference: 
mmoloney