A comparison of the Still-Gennari and Ando HWE-methodologies with α,β-unsaturated aldehydes; unexpected results with stannyl substituted systems

Symplectic ID: 
50448
Source: 
Scopus
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Saturday, 14 March, 2026 - 23:54
DOI: 
10.1016/j.tetlet.2003.08.095
Publication Date: 
Monday, 13 October, 2003
First Page: 
7735
Last Page: 
7740
Authors: 
Franci, X
Martina, SLX
McGrady, JE
Webb, MR
Donald, C
Taylor, RJK
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Abstract: 
Still-Gennari reactions have been carried out on a range of E- and Z-3-substituted propenals. In all cases, with the exception of Z-3-stannyl systems, good Z-stereoselectivity was observed. By contrast, the Ando procedure gives reasonable Z-stereoselectivity with all systems studied, including those with a cis-disposed stannyl substituent. © 2003 Elsevier Ltd. All rights reserved.
ISSN: 
0040-4039
Journal Title: 
Tetrahedron Letters
Volume: 
44
Issue: 
42
ID at Source: 
2-s2.0-0141682281
Publication Status: 
Published
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chem0606