Chemoselective debenzylation of N-benzyl tertiary amines with ceric ammonium nitrate

Symplectic ID: 
110603
Source: 
Scopus
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Sunday, 26 July, 2026 - 05:49
DOI: 
10.1039/b006852g
Publication Date: 
Friday, 1 December, 2000
First Page: 
3765
Last Page: 
3774
Authors: 
Bull, SD
Davies, SG
Fenton, C
Mulvaney, AW
Shyam Prasad, R
Smith, AD
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0
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Abstract: 
Treatment of a range of N-benzyl tertiary amines with aqueous eerie ammonium nitrate results in N-debenzylation to afford the corresponding secondary amine. Chemoselective mono-W-debenzylation of N-benzyl tertiary amines is shown to occur in the presence of N-benzyl amides, O-benzyl ethers, O-benzyl esters, O-benzyl phenolates and 5-benzyl ethers. © The Royal Society of Chemistry 2000.
ISSN: 
1470-4358
Journal Title: 
Journal of the Chemical Society, Perkin Transactions 1
Issue: 
22
ID at Source: 
2-s2.0-0034700386
Publication Status: 
Published
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