DABSO-based, three-component, one-pot sulfone synthesis.

Symplectic ID: 
441788
Source: 
PubMed
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1
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Saturday, 4 July, 2026 - 22:11
DOI: 
10.1021/ol403122a
Publication Date: 
Friday, 3 January, 2014
First Page: 
150
Last Page: 
153
Keywords: 
Dapsone
Epoxy Compounds
Hydrocarbons, Halogenated
Molecular Structure
Organometallic Compounds
Sulfones
Authors: 
Deeming, AS
Russell, CJ
Hennessy, AJ
Willis, MC
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0
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Abstract: 
The addition of Grignard reagents or organolithium reagents to the SO2-surrogate DABSO generates a diverse set of metal sulfinates, suitable for direct conversion to sulfone products. The metal sulfinates can be trapped in situ with a wide range of C-electrophiles, including alkyl, allyl, and benzyl halides, epoxides, and (hetero)aryliodoniums.
Journal Title: 
Org Lett
eISSN: 
1523-7052
Volume: 
16
Issue: 
1
ID at Source: 
24308313
Publication Status: 
Published
Open access: 
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SSO preference: 
chem0368